Philadelphia marriages are available to view on FamilySearch
Use the catalog and search on place, Philadelphia, keyword marriages
You can browse through the images and it is easy when you have the year and certificate number. You can do this from home for the Philadelphia records.
https://tinyurl.com/y7thu4az
Marriages earlier than 1915 are in a different set.
I located the divorce record in the 2nd marriage records from 1931 and sent you a private message.

Barbara Rice
Minneapolis MN
Searching
Kupferschmidt - Radziechow and Philadelphia
Rusonik - Polotsk, Vitebsk
Rehfeld>Rayfield - Gollub-Dobrzyn
Rohssler - Krakow
Zuchovitz - Stolpce, Belarus and Woodbine, NJ